湖南寒婆坳矿区热变质煤结构演化及其矿物学特征响应   总被引：1，自引：0，他引：1  

李焕同  王楠  朱志蓉  石媛  莫佳峰  张卫国  方世跃 《地质学报》2020,94(11):3503-3514

采用X射线荧光光谱(XRF)、差热分析(DTA)、扫描电子显微镜(SEM)、高分辨透射电镜(HRTEM)、X射线衍射(XRD)和拉曼光谱(Raman)等表征手段对湖南寒婆坳矿区热变质煤的化学组分、物理性质、结构演化与其矿物学特征响应进行了研究。结果表明：岩浆侵入体的热力及构造应力作用促进煤化程度升高逐渐转变为隐晶质石墨，氢、碳原子数目比(H/C)逐渐降低，矿物主要为伊利石、绿泥石、叶蜡石、石英及黄铁矿等；随变质程度增加，真密度升高，孔隙度与电阻率降低；在400℃之后，失重曲线下降缓慢且斜率变小，显示深度裂解与脱落较少。 d 002、 L a、 L c的演化趋势呈非线性变化，显示煤有机大分子结构向石墨化演化的过程中呈现“跃变”；隐晶质石墨样品的晶体结构主要为2H型石墨结构，不同程度地含有3R多型，石墨化度为0. 47~0. 84，石墨晶体轴长 a 为0. 2469~0. 2471 nm， c 为0. 6738~0. 6762 nm，晶胞体积 V 为0. 03562~0. 03570 nm3，显示靠近岩体晶胞体积减小；随着变质程度升高， L a、 L c迅速增加，堆叠层数急剧增大，煤内部空间结构趋于有序化，拉曼参数 A D1、 P (G- D1)逐渐降低。  相似文献   

海洋微塑料检测技术研究进展   总被引：1，自引：0，他引：1  

王俊豪  梁荣宁  秦伟 《海洋通报》2019,38(6):601-612

海洋微塑料污染目前已成为全球性的环境问题,近年来海洋微塑料检测技术越来越受到人们的关注。本文简要总结了微塑料样品采集及处理方法,并从检测方法的角度系统综述了近些年来微塑料检测技术的研究进展,涉及目视分析法、光谱法(如傅立叶变换红外光谱法和拉曼光谱法)、热分析法以及其他分析方法等(如质谱法以及扫描电子显微镜-能谱仪联用法)。本文简要评价了各类检测方法的优缺点,以期为海洋微塑料检测技术的发展提供参考,并探讨了未来海洋微塑料检测技术的发展方向。  相似文献   

南海大洋钻探及海洋地质与地球物理前沿研究新突破   总被引：2，自引：2，他引：0  

林间  李家彪  徐义刚  孙珍  夏少红  黄小龙  解习农  李春峰  丁巍伟  周志远  张帆  罗怡鸣 《海洋学报》2019,41(10):125-140

南海是西太平洋地区规模最大且具有代表性的边缘海盆地之一。经过近几十年的研究积累，尤其是通过实施5个国际大洋钻探航次(1999–2018年)与国家自然科学基金委“南海深海过程演变”重大研究计划(2011–2019年)，我国科学家获得了大量宝贵的第一手资料，取得了一系列创新进展与重大突破，标志着南海海洋地质与地球物理研究正走向国际前沿。重要研究成果包括:(1)新提出南海是“板缘张裂”盆地，与经典的大西洋型陆缘模式不同；(2)大洋钻探首次获取了基底玄武岩样品，结合中国在南海首次深拖地磁测量实验，精确测定了南海海盆玄武岩年龄，揭示南海海盆从东向西分段扩张；(3)大洋钻探结果发现南海陆缘岩石圈减薄之初岩浆迅速出现，未发现缓慢破裂造成的蛇纹岩出露；(4)发现南海扩张结束后仍存在大量岩浆活动，可能受控于多种构造与地幔因素；(5)地球化学证据与地球动力学模拟都显示南海岩浆的形成受到周边俯冲带的影响。目前我国的海洋地球科学正在进入崭新的发展阶段，有望以南海为基点，开始拓展到周边大洋，通过主导大型研究计划以及建设我国大洋钻探平台，以提升我国在南海、西太平洋与印度洋海洋地质科学研究的实质性影响力与引领地位。  相似文献   

干热岩钻探关键技术探索   总被引：1，自引：0，他引：1       下载免费PDF全文

王勇军  代娜  郑宇轩 《山东国土资源》2019,35(2)

干热岩是国际公认的高效低碳清洁能源,近年来,随着国家对清洁能源勘探开发的提倡和支持,国内开展了一些干热岩勘探工作。干热岩钻探是前期获取地质资料进行资源量计算及后期开发利用的关键部分。现阶段国内在干热岩钻探工艺技术方面还没有形成体系,大多借用石油钻井行业及地质钻井行业的一些工艺技术,但干热岩钻探钻遇地层温度普遍较高,且大部分孔段均为坚硬的花岗岩地层,因此如何在高温环境下保持钻井液性能,保证其携带岩屑及维护孔壁稳定的功效,在坚硬的花岗岩层中如何提高钻进效率,实现高效钻进,钻遇破碎地层时如何维护孔壁稳定,实现护壁堵漏等问题,该文结合国内已施工的部分干热岩钻探工程,对国内干热岩钻探所采取的工艺技术进行了探索,研制了抗高温配方的钻井液,使用转盘回转+孔底动力钻具复合钻进,在钻井液中加入抗高温封堵剂,可有效提高干热岩钻探效率,以期促进干热岩钻探工艺技术的研究、应用和推广。  相似文献   

强造斜致绳索取心钻具折断分析     

卢秋平 《地质与勘探》2020,56(2):445-450

在定向钻探固体矿产领域,通常在造斜段使用螺杆钻具,大部分的工作量采用取心回转钻进。造斜段使用螺杆钻具,钻杆不回转,受力较简单;如遇强造斜转换绳索取心钻具稳斜钻进,下部钻具组合容易出现回转困难、下不到底的技术难题,甚至出现丝扣折断事故。为避免强造斜对绳索取心钻具的影响,本文通过建立强造斜段对绳索取心钻具的几何约束变形模型,量化分析强造斜段岩心外管长度与造斜强度、环空间隙之间的约束关系,提供了可快速预判下部钻具参数能否满足强造斜安全钻进的方法。该方法在山东某铁矿定向孔的强造斜致下部钻具折断的事故处理中,通过对绳索取心钻具安全计算模型校核和调整钻具参数,实现了绳索取心钻具通过造斜率0.62°/m的强造斜段安全钻进至靶点,证明对强造斜绳索取心工具安全钻进预测和事故处理计算具有指导意义。  相似文献   

Terrestrial heat flow and lithospheric thermal structure in the Chagan Depression of the Yingen-Ejinaqi Basin,north central China     

Yinhui Zuo  Shu Jiang  Shihu Wu  Wei Xu  Jiong Zhang  Renpeng Feng  Meihua Yang  Yongshui Zhou  M. Santosh 《Basin Research》2020,32(6):1328-1346

The Chagan Depression in the Yingen-Ejinaqi Basin, located at the intersection of the Paleo-Asian Ocean and the Tethys Ocean domains is an important region to gain insights on terrestrial heat flow, lithospheric thermal structure and deep geodynamic processes. Here, we compute terrestrial heat flow values in the Chagan Depression using a large set of system steady-state temperature data from four representative wells and rock thermal conductivity. We also estimate the “thermal” lithospheric thickness, mantle heat flow, ratio of mantle heat flow to surface heat flow and Moho temperature to evaluate the regional tectonic framework and deep dynamics. The results show that the heat flow in the Chagan Depression ranges from 66.5 to 69.8 mW/m², with an average value of 68.3 ± 1.2 mW/m². The Chagan Depression is characterized by a thin “thermal” lithosphere, high mantle heat flow, and high Moho temperature, corresponding to the lithospheric thermal structure of “cold mantle and hot crust” type. We correlate the formation of the Yingen-Ejinaqi Basin to the Early Cretaceous and Cenozoic subduction of the western Pacific Plate and the Cenozoic multiple extrusions. Our results provide new insights into the thermal structure and dynamics of the lithospheric evolution in central China.  相似文献   

Study on deepwater conductor jet excavation mechanism in cohesive soil     

《Applied Ocean Research》2019

Conductor casing jetting technique has been increasingly applied in deepwater drilling. The insight into the jetting excavation mechanisms is critical in guiding a successful conductor casing jetting operation. The real- time continuous jet excavation process is simulated with the volume of fluid (VOF) multiphase method of CFD (Computational Fluid Dynamics) ANSYS Fluent calculation software in the current study. The cohesive soil is modelled by using a kind of viscous fluid with Herschel-Bulkley model. In addition, a laboratory half round nozzle jet excavation test is designed for verification by comparison of the observed jet excavation profile with the numerical results. The sensitivity parameters affecting the conductor jetting excavation mechanism in cohesive soil are thus investigated. It is found that the application of Herschel-Bulkley (HB) model for cohesive soil and the VOF method of Fluent can provide a good simulation of jet excavation process. The maximum excavation depth can be determined by the undrained ultimate bearing capacity of the circular foundation with a bearing capacity factor of 6.7. The nozzle position, jet velocity and soil strength have significantly influence on the depth and width of the jet excavation profile in conductor oblique jet.  相似文献   

高效钻杆润滑脂研制及其在川藏铁路勘察中的应用          下载免费PDF全文

熊正强  陶士先  张德龙  邹志飞 《探矿工程》2020,47(11):7-11

针对地质钻探深孔或水平孔失返性漏失时钻具磨损及钻进效率低的问题，以白油、钠基稠化剂与粘结性材料等为原料，采用一步法研制了一种高效钻杆润滑脂，并在川藏铁路昌都段定测勘察水平孔现场应用中取得显著效果，有力支撑服务了川藏铁路大位移水平孔施工。室内评价及现场应用结果表明，该润滑脂具有耐低温（-16 ℃）、易涂抹、良好的粘附性与润滑性以及高性价比特点，能长时间保护钻具，而且其润滑效果与国外同类产品相当。  相似文献   

地质钻探废弃冲洗液污染特性及脱稳技术研究          下载免费PDF全文

张统得  蒋炳  严君凤 《探矿工程》2020,47(4):134-139

废弃冲洗液无害化处理是落实绿色勘查理念的一项重要工作。通过室内测试分析与现场调研，对地质钻探不同领域的钻孔废弃冲洗液进行污染特性研究，了解其基本性质以及对环境的影响方式。结合湘桃地2井废弃冲洗液开展脱稳技术室内研究，对破胶剂及絮凝剂进行了优选，并获得了脱稳处理的基础配方。实验结果表明，经过处理后废弃冲洗液能实现快速脱稳絮凝，COD、悬浮物、色度等污染指标大幅下降，为下一步深度处理实现无害化排放创造了有利条件。  相似文献   

Microstructure Evolution of Organic Matter and Clay Minerals in Shales with Increasing Thermal Maturity     

GU Yuantao  LI Xiaoxi  YANG Shuguang  WAN Quan 《《地质学报》英文版》2020,94(2):280-289

As the two important components of shale, organic matter(OM) and clay minerals are usually thought to strongly influence the hydrocarbon generation, enrichment and exploitation. The evolution process of OM and clay minerals as well as their interrelationship over a wide range of thermal maturities are not completely clear. Taking Yanchang(T_3y), Longmaxi(S_1l) and Niutitang(?_1n) shales as examples, we have studied the microstructure characteristics of OM and clay minerals in shales with different thermal maturities. The effects of clay minerals and OM on pores were reinforced through sedimentation experiments. Using a combination of field emission scanning electron microscopy(FESEM) and low-pressure N_2 adsorption, we investigated the microstructure differences among the three shales. The results showed that both OM and clay minerals have strong effects on pores, and small mesopore(2–20 nm) is the dominant pore component for all three samples. However, the differences between the three samples are embodied in the distribution of pore size and the location. For the T_3y shale, clay minerals are loosely arranged and develop large amounts of pores, and fine OM grains often fill in intergranular minerals or fractures. Widespread OM pores distribute irregularly in S_1l shale, and most of the pores are elliptical and nondirectional. The ?_1n shale is characterized by the preferred orientational OM-clay aggregates, and lots of pores in the composites are in the mesopore range, suggesting that over maturity lead to the collapse and compaction of pores under huge pressure of strata. The results of the current research imply that with increasing thermal maturity, OM pores are absent at low maturity(T_3y), are maximized at high maturity(S_1l) and are destroyed or compacted at over-mature stage(?_1n). Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon generation of shale.  相似文献